Generally, less active metals (Cu, Ni, Zn…) are electrolyzed in aqueous liquid, but highly active metals such as rare earth elements and light metals are not. This is because hydrogen is gassed on electrode before deposition of metal in aqueous solution. Electrodeposition of rare earth elements is only possible by fused salt electrolysis at high temperature. Therefore, researchers have studied electrodeposition of one or two rare earth elements in molten salts and special organic solvents.
One of the major advantages of ionic liquids in electrodeposition is that electrochemical processes are carried out at low temperatures close to room temperature. This can reduce the energy loss of electrochemical processes that must be carried out at high temperatures. Therefore, some researchers have used various ionic liquids for electrodeposition of various active metallic elements at low temperatures. However, the liquids are highly hygroscopic and thus, an inert gas-filled space must be provided to prevent moisture for the elctrodeposition, which makes them difficult to be applied to industrial applications.
Use of 1-ethyl-3-methyl-imidazolium fluoroborate (EMIMBF4) ionic liquids has the potential for electrolysis of rare earth elements with no special conditions.
An Hyo Song, a researcher at the General Assay Office, has proposed a new method for the co-electrodeposition of dysprosium and terbium using EMIMBF4 ionic liquid.
The experiments demonstrated that the electrodeposition of dysprosium and terbium ions in EMIMBF4 ionic liquids is an irreversible and simultaneous process. He used the measured data to ensure that the electrolyte composition and diffusivity are reasonable, and newly determined the kinetic diffusion coefficients of these chemical reactions from cyclic voltammetric and chronoamperometric analyses.
For more information, please refer to his paper “ Simultaneous electrodeposition behavior of dysprosium and terbium in 1-ethyl-3-methyl-imidazolium tetrafluoroborate ionic liquid” in “ Journal of the Indian Chemistry Society” (SCI).
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