Preparation of copper nanoparticles have depended on liquid-phase reduction, where copper sulfate as raw material is dissolved in deionized water and a certain amount of dispersant is added before they were heated under stirring to reach reduction reaction temperature and reducing agent is dropped and mixed to produce copper nanoparticles.
Then, mixing reducing agents takes long while the reduction rate of copper ions is very fast (reduction reaction is already initiated before required amount of reducing agent is mixed). This results in non-uniform nucleation-crystalline growth, thus copper nanoparticles unhomogeneous in size being obtained.
After the reduction reaction, the copper nanoparticles dispersed in liquid phase are separated from the liquid phase using a high-speed centrifuge, which are diluted again in deionized water, and centrifugation washing process is repeated several times, so oxidation by atmospheric oxygen is easily achieved.
Kim Song Chol, a researcher at the Faculty of Materials Science and Technology, prepared relatively uniform-size copper nanoparticles by thoroughly mixing the reactants (copper salt solution + reducing agent solution) at room temperature in the liquid-phase reduction process (based on the fact that reduction reaction never occurs even when copper sulfate aqueous solution and reducing agent solution are mixed below 40ºC) and heating to the reaction temperature under stirring, allowing simultaneous and homogeneous nucleation of crystalline nuclei to be formed in the reaction system.
In addition, he realized separation and wash of produced copper nanoparticles from aqueous solution without a centrifuge, and instead introduced volatile organic solvent into reaction system to encapsulate the produced copper nanoparticles. By doing so, he ensured their surfaces are protected as soon as the copper nanoparticles are produced, and also simplified the separation and washing process.
The proposed technique can reduce the production cost of copper nanoparticles and increase the rate of recovery, particle size homogeneity and oxidation stability. In addition, it is a great potential for practical applications as producing copper nanoparticles as there is no need for expensive high-speed centrifuges. It is also useful for mass production of copper nanoparticles as lubricating oil additives.
You can find more information in his paper “A new method to improve homogeneity and oxidation stability of Cu nanoparticles for lubricant additive in liquid phase reduction process” in “ Materials Research Express ” (SCI).
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