Development and use of natural energy plays an important role in guaranteeing the sustainable development of economy and satisfying the energy demands. In this field, study on the solar energy is particularly important. Recently, the efficiency of perovskite solar cells (PSCs) which have become the focus of solar energy development almost reached the efficiency of silicon solar cells and therefore a lot of efforts are being made to ensure the stability of solar cells.
The stability of PSCs primarily depends on the stability of perovskite which performs the function of light absorber in devices. For this reason, many researchers are trying to improve the heat and humidity stability of perovskite.
Recently, it has been found that ion liquid, which has been studied in several fields including medicine due to its special properties such as high viscosity, low vapor pressure and incombustibility, can be used as an additive or a solvent for perovskite precursor to improve the performance and stability of PSCs.
Ion liquid, well known as an eco-friendly harmless solvent, has polarity that can solve perovskite precursor, so it can replace the toxic DMF or DMSO that have been conventionally used for fabrication of PSCs.
Kang Jin Hyok, a researcher at the Faculty of Information Science and Technology, investigated the influence of ion liquid methylammonium acetate (MAAc) on the characteristics of perovskite and the performance of hole transport material (HTM)-free PSCs with carbon electrode when it is used as a solvent of precursor for preparing perovskite.
The perovskite was prepared by solid–gas reaction between dimethylammonium lead iodide (DMAPbI3) and methylamine (MA). DMAPbI3 was solved by ion liquid MAAc instead of DMF and it was used as a precursor.
The perovskite film based on ion liquid was more uniform and denser than the one based on DMF, thus improving the crystallinity and crystal size of perovskite. The analysis result showed that the nonradiative recombination of cells decreased and the open circuit voltage could be improved when using MAAc instead of DMF.
For further details, you can refer to his paper “The characteristics of hole-transport material-free perovskite solar cells with carbon electrode made by using ion liquid methylammonium acetate solvent” in “Results in Optics” (SCI).
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