Zeolites have been widely used in various industrial fields including the chemical industry due to their unique catalytic properties and excellent adsorption and ion exchange capabilities, and there is a constant interest in developing zeolites with different performances, reducing their production costs and making their synthesis easier.
ZSM-5 zeolite, synthesized in the early 1970s, has a large specific area and high thermal and mechanic stability, and it has a porous structure consisting of alternating three-dimensional straight pore channels and Z-type pore channels, which makes it widely used in various fields, such as the industry of fine chemicals, oil chemistry, environmental protection, etc. Especially, it has been used as a catalyst, a molecular sieve and an adsorbent in the chemical industry.
ZSM-5 zeolite is usually synthesized by hydrothermal synthesis using silica raw materials, alumina raw materials and organic templates as synthetic materials. Aluminum sulfate, aluminum nitrate and sodium aluminate are widely used as raw materials of alumina source for ZSM-5 zeolite synthesis, while silica sol, water glass, etc. are widely used as silica source. In addition, quaternary ammonium salts, alcohols, amines and amino alcohols are used as organic templates. The choice of an organic template will determine the cost of ZSM-5 zeolite, which limits the industrial production of ZSM-5 zeolite.
Sin Hyok, a researcher at the Faculty of Chemical Engineering, has proposed a method of synthesizing ZSM-5 zeolite using water glass, aluminum sulfate and triethylamine as a silica source, an alumina source and a template, respectively, and determined the optimum crystallization condition for synthesizing ZSM-5 zeolite using such materials as mentioned above.
He defined the molar ratio of raw materials in aluminosilicate gel as 6Na2O:50SiO2:1Al2O3:1 300H2O:10C6H15N and performed hydrothermal crystallization at 100-150℃ for 30-42 hours. Then, he determined the optimum crystallization temperature and time, with relative crystallinity of 95% and solid product yield of more than 0.9.
He found that in a certain temperature range, the relative crystallinity and solid product yield increased with increasing crystallization time.
The proposed method is a new approach to prepare ZSM-5 zeolite from commercially accessible and relatively inexpensive raw materials.
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